Crystallization Kinetics and Morphology Relations on Thermally Annealed Bulk Heterojunction Solar Cell Blends Studied by Rapid Heat Cool Calorimetry (RHC)

Fatma Demir, Niko Van Den Brande, Sabine Bertho, Eszter Voroshazi, Jean Manca, Dirk Vanderzande, Paul Heremans, Bruno Van Mele, Guy Van Assche

Research output: Chapter in Book/Report/Conference proceedingConference paper

1 Citation (Scopus)

Abstract

Optimizing the post-production annealing conditions of polymer:fullerene bulk heterojunction solar cells is vitally important, not only for fine-tuning the morphology - thus increasing the efficiency - but also for retaining the desired morphology during long-term operation. However, optimal conditions for annealing temperatures and times can only be chosen, once thermal transition temperatures and annealing kinetics of the blends are well-known. For instance, for systems with glass transition temperatures (Tg) lower than the maximum device operation temperature of 80°C, the mobility needed for morphology coarsening is present, leading to efficiencies decreasing in the course of time. Using advanced fast-scanning thermal analysis techniques, the formation of nuclei and growth of crystals during heating or cooling can be reduced or avoided, and thus, the fast crystallization processes occurring during annealing of the polymer:fullerene blends can be followed. In this study, non-isothermal and isothermal crystallization kinetics of the P3HT:PCBM (poly(3-hexyl thiophene: [6,6] -phenyl C61 - butyric acid methyl ester) and P3HT:bis-PCBM blends are investigated and compared by using Rapid Heating Cooling Calorimetry (RHC).
Original languageEnglish
Title of host publicationSPIE Photonics Europe
PublisherSPIE, Brussels, Belgium
Publication statusPublished - 17 Apr 2012
EventSPIE Organic Photonics V - Brussels, Belgium
Duration: 16 Apr 201218 Apr 2012

Conference

ConferenceSPIE Organic Photonics V
CountryBelgium
CityBrussels
Period16/04/1218/04/12

Keywords

  • Bulk Heterojunction Solar Cells
  • P3HT:PCBM
  • P3HT:bis-PCBM
  • Crystallization Kinetics
  • RHC

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