Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Petr Simon; Roman Jambor; Ales Ruzicka; Antonin Lycka; Frank De Proft; Libor Dostál

Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Petr Simon, Roman Jambor, Ales Ruzicka, Antonin Lycka, Frank De Proft, Libor Dostál

Research output: Contribution to journal › Article › peer-review

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Abstract

NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.

Original language	English
Pages (from-to)	5140-5143
Number of pages <span style="color:red"p> <font size="1.5"> ✽ </span> </font>	4
Journal	Dalton Transactions
Volume	41
Issue number	17
Publication status	Published - 2012

Keywords

MAIN-GROUP ELEMENTS

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abstract = "NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.",

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author = "Petr Simon and Roman Jambor and Ales Ruzicka and Antonin Lycka and {De Proft}, Frank and Libor Dost{\'a}l",

year = "2012",

language = "English",

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journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

AU - Simon, Petr

AU - Jambor, Roman

AU - Ruzicka, Ales

AU - Lycka, Antonin

AU - De Proft, Frank

AU - Dostál, Libor

PY - 2012

Y1 - 2012

N2 - NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.

AB - NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.

KW - MAIN-GROUP ELEMENTS

M3 - Article

VL - 41

SP - 5140

EP - 5143

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 17

ER -

Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Abstract

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