A new insight into the contested origin of the absence of radical reaction in the pyrolysis of CF2ClCH3 is given. This chain reaction would be too slow compared with the molecular reaction because of a too slow homogeneous initiation leading to a too fast wall recombination of the Cl atom chain carriers.
|Number of pages||7|
|Journal||International Journal of Chemical Kinetics|
|Publication status||Published - 1999|
Bibliographical noteInternational Journal of Chemical Kinetics 31 (1999) 283-289.
- reaction mechanism
- chlorinated and fluorinated hydrocarbons
- heterogeneous termination