Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Michal Aman; Libor Dostál; Aleš Růžička; Jiří Tydlitát; Jens Beckmann; Jan Turek; Roman Jambor

doi:10.1039/D1CC06173A

Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Michal Aman, Libor Dostál, Aleš Růžička, Jiří Tydlitát, Jens Beckmann, Jan Turek, Roman Jambor

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Abstract

A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.

Original language	English
Pages (from-to)	12992-12995
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	96
DOIs	https://doi.org/10.1039/D1CC06173A
Publication status	Published - 14 Dec 2021

Bibliographical note

Funding Information:
We would like to acknowledge the Czech Science foundation (project 20-10417S) for financial support. J. Turek gratefully acknowledges the financial support of the Research Foundation– Flanders (FWO; Project No. 12Y7721N) and the computational resources and services provided by the VUB-HPC (VSC Tier-2 cluster of the Flemish Supercomputer Center) funded by the Vrije Uni-versiteit Brussel, FWO and the Flemish Government.

Publisher Copyright:
© The Royal Society of Chemistry.

Copyright:
Copyright 2022 Elsevier B.V., All rights reserved.

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10.1039/D1CC06173A

ChemCommun_2021-57-12992Accepted author manuscript, 579 KBLicence: Unspecified

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FWOTM1003: Towards a Predictive Conceptual Model for Polymerization of Cyclic Esters Catalyzed by Group 14 Metal Complexes
Turek, J. & Alonso Giner, M.
1/10/20 → 30/09/23
Project: Fundamental

Cite this

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title = "Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol",

abstract = "A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.",

author = "Michal Aman and Libor Dost{\'a}l and Ale{\v s} Rů{\v z}i{\v c}ka and Ji{\v r}{\'i} Tydlit{\'a}t and Jens Beckmann and Jan Turek and Roman Jambor",

note = "Funding Information: We would like to acknowledge the Czech Science foundation (project 20-10417S) for financial support. J. Turek gratefully acknowledges the financial support of the Research Foundation– Flanders (FWO; Project No. 12Y7721N) and the computational resources and services provided by the VUB-HPC (VSC Tier-2 cluster of the Flemish Supercomputer Center) funded by the Vrije Uni-versiteit Brussel, FWO and the Flemish Government. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry. Copyright: Copyright 2022 Elsevier B.V., All rights reserved.",

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doi = "10.1039/D1CC06173A",

language = "English",

volume = "57",

pages = "12992--12995",

journal = "Chemical Communications",

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T1 - Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

AU - Aman, Michal

AU - Dostál, Libor

AU - Růžička, Aleš

AU - Tydlitát, Jiří

AU - Beckmann, Jens

AU - Turek, Jan

AU - Jambor, Roman

N1 - Funding Information: We would like to acknowledge the Czech Science foundation (project 20-10417S) for financial support. J. Turek gratefully acknowledges the financial support of the Research Foundation– Flanders (FWO; Project No. 12Y7721N) and the computational resources and services provided by the VUB-HPC (VSC Tier-2 cluster of the Flemish Supercomputer Center) funded by the Vrije Uni-versiteit Brussel, FWO and the Flemish Government. Publisher Copyright: © The Royal Society of Chemistry. Copyright: Copyright 2022 Elsevier B.V., All rights reserved.

PY - 2021/12/14

Y1 - 2021/12/14

N2 - A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.

AB - A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.

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U2 - 10.1039/D1CC06173A

DO - 10.1039/D1CC06173A

M3 - Article

VL - 57

SP - 12992

EP - 12995

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 96

ER -

Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Abstract

Bibliographical note

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Projects

FWOTM1003: Towards a Predictive Conceptual Model for Polymerization of Cyclic Esters Catalyzed by Group 14 Metal Complexes

Cite this