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Abstract
A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.
Original language | English |
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Pages (from-to) | 12992-12995 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 57 |
Issue number | 96 |
DOIs | |
Publication status | Published - 14 Dec 2021 |
Bibliographical note
Funding Information:We would like to acknowledge the Czech Science foundation (project 20-10417S) for financial support. J. Turek gratefully acknowledges the financial support of the Research Foundation– Flanders (FWO; Project No. 12Y7721N) and the computational resources and services provided by the VUB-HPC (VSC Tier-2 cluster of the Flemish Supercomputer Center) funded by the Vrije Uni-versiteit Brussel, FWO and the Flemish Government.
Publisher Copyright:
© The Royal Society of Chemistry.
Copyright:
Copyright 2022 Elsevier B.V., All rights reserved.
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FWOTM1003: Towards a Predictive Conceptual Model for Polymerization of Cyclic Esters Catalyzed by Group 14 Metal Complexes
1/10/20 → 30/09/23
Project: Fundamental