Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Michal Aman, Libor Dostál, Aleš Růžička, Jiří Tydlitát, Jens Beckmann, Jan Turek, Roman Jambor

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Abstract

A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a κ2Sn,P-chelating ligand for Ru(ii) compounds.

Original languageEnglish
Pages (from-to)12992-12995
Number of pages4
JournalChemical Communications
Volume57
Issue number96
DOIs
Publication statusPublished - 14 Dec 2021

Bibliographical note

Funding Information:
We would like to acknowledge the Czech Science foundation (project 20-10417S) for financial support. J. Turek gratefully acknowledges the financial support of the Research Foundation– Flanders (FWO; Project No. 12Y7721N) and the computational resources and services provided by the VUB-HPC (VSC Tier-2 cluster of the Flemish Supercomputer Center) funded by the Vrije Uni-versiteit Brussel, FWO and the Flemish Government.

Publisher Copyright:
© The Royal Society of Chemistry.

Copyright:
Copyright 2022 Elsevier B.V., All rights reserved.

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