Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques

Erik Van Der Eycken; G Carlens; Joris Messens; Yn Zhao; G. Bauw; Johan Van Der Eycken; P. Sandra; Marc Van Montagu

Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques

Erik Van Der Eycken, G Carlens, Joris Messens, Yn Zhao, G. Bauw, Johan Van Der Eycken, P. Sandra, Marc Van Montagu

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A modified pathway to synthesize on large scale L-xylo-hexos-2-ulose (L-sorbosone), a potential intermediate in the biosynthesis of L-ascorbic acid in some plants, is described. The determination of the purity by thin-layer chromatography, high-performance liquid chromatography, capillary gas chromatography (cGC) and cGC-mass spectrometry (MS) is discussed. The product is for the first time unambiguously characterized by C-13 NMR and electrospray MS.

Original language	English
Pages (from-to)	261-269
Number of pages	9
Journal	Journal of Chromatography A
Volume	811
Issue number	1-2
Publication status	Published - 19 Jun 1998

Keywords

carbohydrates
sorbosone

Cite this

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title = "Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques",

abstract = "A modified pathway to synthesize on large scale L-xylo-hexos-2-ulose (L-sorbosone), a potential intermediate in the biosynthesis of L-ascorbic acid in some plants, is described. The determination of the purity by thin-layer chromatography, high-performance liquid chromatography, capillary gas chromatography (cGC) and cGC-mass spectrometry (MS) is discussed. The product is for the first time unambiguously characterized by C-13 NMR and electrospray MS.",

keywords = "carbohydrates, sorbosone",

author = "{Van Der Eycken}, Erik and G Carlens and Joris Messens and Yn Zhao and G. Bauw and {Van Der Eycken}, Johan and P. Sandra and {Van Montagu}, Marc",

year = "1998",

month = jun,

day = "19",

language = "English",

volume = "811",

pages = "261--269",

journal = "Journal of Chromatography. A",

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Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques. / Van Der Eycken, Erik; Carlens, G; Messens, Joris; Zhao, Yn; Bauw, G.; Van Der Eycken, Johan; Sandra, P.; Van Montagu, Marc.

In: Journal of Chromatography A, Vol. 811, No. 1-2, 19.06.1998, p. 261-269.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques

AU - Van Der Eycken, Erik

AU - Carlens, G

AU - Messens, Joris

AU - Zhao, Yn

AU - Bauw, G.

AU - Van Der Eycken, Johan

AU - Sandra, P.

AU - Van Montagu, Marc

PY - 1998/6/19

Y1 - 1998/6/19

N2 - A modified pathway to synthesize on large scale L-xylo-hexos-2-ulose (L-sorbosone), a potential intermediate in the biosynthesis of L-ascorbic acid in some plants, is described. The determination of the purity by thin-layer chromatography, high-performance liquid chromatography, capillary gas chromatography (cGC) and cGC-mass spectrometry (MS) is discussed. The product is for the first time unambiguously characterized by C-13 NMR and electrospray MS.

AB - A modified pathway to synthesize on large scale L-xylo-hexos-2-ulose (L-sorbosone), a potential intermediate in the biosynthesis of L-ascorbic acid in some plants, is described. The determination of the purity by thin-layer chromatography, high-performance liquid chromatography, capillary gas chromatography (cGC) and cGC-mass spectrometry (MS) is discussed. The product is for the first time unambiguously characterized by C-13 NMR and electrospray MS.

KW - carbohydrates

KW - sorbosone

M3 - Article

VL - 811

SP - 261

EP - 269

JO - Journal of Chromatography. A

JF - Journal of Chromatography. A

SN - 0021-9673

IS - 1-2

ER -

Synthesis of L-xylo-hexos-2-ulose (L-sorbosone) and its characterisation by chromatographic and spectroscopic techniques

Abstract

Keywords

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