From a 2,1‐Benzazaarsole to Elusive 1‐Arsanaphthalenes in One Step

Vít Kremláček, Milan Erben, Roman Jambor, Aleš Růžička, Jan Turek, Elena Rychagova, Sergey Ketkov, Libor Dostál

Onderzoeksoutput: Articlepeer review

11 Citaten (Scopus)
48 Downloads (Pure)

Samenvatting

The 2,1-benzazaarsole (1) showed a diene-like reactivity towards selected alkynes RC≡CR (R=CO 2 Me, C 5 F 4 N) thus forming 1-arsa-1,4-dihydro-iminonaphthalenes 2 a and 3 a as hardly isolable intermediates, that underwent facile CH→NH proton migration leading to before elusive substituted 1-arsanaphthalenes 2 b and 3 b that could be completely structurally characterized.

Originele taal-2English
Pagina's (van-tot)5668-5671
Aantal pagina's4
TijdschriftChemistry - a European Journal
Volume25
Nummer van het tijdschrift22
DOI's
StatusPublished - 17 apr 2019

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