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Mixed matrix membranes (MMM) incorporating metal-organic framework (MOF) fillers have gained increasing attention in addressing environmental and sustainability challenges. Hierarchical materials combining pore sizes of different length scales are expected to facilitate molecular diffusion and mass transfer for the optimization of catalysis and separation processes. Herein, a novel preparation method for hierarchical ZIF-8 (H-ZIF-8) particles is presented for the synthesis of polyimide (PI)-based MMMs with good compatibility between filler and polymer. Gas permeability measurements of polyimide-Matrimid (R)/H-ZIF-8 MMMs showed 4-fold improvements in permeability of both CO2 and CH4 coupled with a marked increase in selectivity and plasticization resistance for MMM with 30 wt% H-ZIF-8 loading. Gas transport analysis in these MMMs revealed that the enhanced gas separation performance of the MMMs can be related to the imidazolate modification of the PI structure and the hierarchical structure of H-ZIF-8, as confirmed by N-2, Ar, mercury porosimetry, SEM, TEM analysis. CO2 permeability for all MMMs increases with increasing CO2 concentration and by decreasing temperature. The proof of concept, as demonstrated in this study, could be extended for the preparation of other hierarchical ZIFs and related MMMs.
Originele taal-2 | English |
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Artikelnummer | 118943 |
Tijdschrift | Journal of Membrane Science |
Volume | 620 |
DOI's | |
Status | Published - 15 feb 2021 |
Bibliografische nota
Funding Information:S. Shahid thanks the University of Bath for the academic research funds to support this work. L. H. W. thanks the FWO-Vlaanderen for a postdoctoral research fellowship (12M1415 N). J. A. M. gratefully acknowledges financial support from the Flemish Government for long-term Methusalem funding. J. A. M. and I. F. J. V. acknowledge the Belgian Government for IAP-PAI networking.
Publisher Copyright:
© 2020
Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.
Vingerafdruk
Duik in de onderzoeksthema's van 'Hierarchical ZIF-8 composite membranes: Enhancing gas separation performance by exploiting molecular dynamics in hierarchical hybrid materials'. Samen vormen ze een unieke vingerafdruk.Projecten
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SRP6: SRP (Zwaartepunt): exploitatie van de voordelen van de Orde in Opsluiting voor een groenere chemie
Desmet, G., Denayer, J., Denayer, J., Desmet, G. & Denayer, J.
1/11/12 → 31/10/22
Project: Fundamenteel