Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Petr Simon, Roman Jambor, Ales Ruzicka, Antonin Lycka, Frank De Proft, Libor Dostál

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21 Citaten (Scopus)

Samenvatting

NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.
Originele taal-2English
Pagina's (van-tot)5140-5143
Aantal pagina's4
TijdschriftDalton Transactions
Volume41
Nummer van het tijdschrift17
StatusPublished - 2012

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