Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones

Corinne De Dobbeleer; Jiri Pospisil; Freija De Vleeschouwer; Frank De Proft; Istvan E. Marko

Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones

Corinne De Dobbeleer, Jiri Pospisil, Freija De Vleeschouwer, Frank De Proft, Istvan E. Marko

Onderzoeksoutput: Article › peer review

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The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

Originele taal-2	English
Pagina's (van-tot)	2142-2144
Aantal pagina's	3
Tijdschrift	Chemical Communications
Nummer van het tijdschrift	16
Status	Published - 2009

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@article{212eb09e23e247f9bbfa2d3eebd1bbb1,

title = "Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones",

abstract = "The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.",

keywords = "electrophilicity",

author = "{De Dobbeleer}, Corinne and Jiri Pospisil and {De Vleeschouwer}, Freija and {De Proft}, Frank and Marko, {Istvan E.}",

year = "2009",

language = "English",

pages = "2142--2144",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones

AU - De Dobbeleer, Corinne

AU - Pospisil, Jiri

AU - De Vleeschouwer, Freija

AU - De Proft, Frank

AU - Marko, Istvan E.

PY - 2009

Y1 - 2009

N2 - The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

AB - The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

KW - electrophilicity

M3 - Article

SN - 1359-7345

SP - 2142

EP - 2144

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones

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